Silicone is the very last type of caulk i would ever use no good at all exterior around window and doors. Silicone is the best sealant for glass tile and metal while polyurethane works well on natural products such as wood.

Chemistry And Benefits Of Ms Polymer Sealant
Polyurethane sealant vs silicone. Best caulk sealant osi quad vs silicone and polyurethane. A lesson in chemistry. In some cases the silicone sealant stands out more than the polyurethane sealant. Silicone sealants so each project should be evaluated based on its own unique characteristics. Polyurethane is an organic material. For example with polymer the elongation at break point can stretch up to 350 whereas many silicone alternatives may only stretch to around 280.
While a silicone joint could last more than 20 years. Silicone fails when applied to wood. The primary difference is at the chemical level. The difference boils down to the fact that silicone sealants wont break down as a result of uv exposure. Polyurethane is an organic material. I use quad for my siding caulk never have had a problem with it and can get it to color match my steel siding.
Despite their common purpose there are a few major differences between them. The primary difference is at the chemical level. Silicone is an inorganic material. This difference means each material will break down differently over time and react differently in different environments. Polyurethane succeeds with this material as well because it dries hard. Uv stability and reversion.
Silicone sealants last longer than polyurethane sealants. Typically a polyurethane sealant will produce effects that last between 5 and 10 years. The hard drying makes polyurethane a lot more difficult to apply as it stiffens when out of the tube. Silicone is an inorganic material. Sealant formulations are constantly changing so it is imperative to keep up with the latest advances. Polyurethane sealants for example support for ultraviolet rays but do not withstand temperatures above 100 degrees celsius and have no chemical resistance since it is organic.
As their names suggest polyurethane and silicone sealants are drastically different chemically. Silicone and polyurethane are two popular types of sealant. In this category there are some impressive numbers in regards to strength and durability. Why is sealant chemistry important. The effects of breakdown of silicone and polyurethane depend on the sealants chemical makeup. For example there is far better uv resistance in urethane sealants compared to what existed when the building was constructed.
Polyurethane is an organic material while silicone is inorganic.